3M Canada Company
1840 Oxford Street East, Post Office Box 5757
London, Ontario N6A 4T1
Medical Emergency Telephone: (519) 451-2500, Ext. 2222
Transportation Emergency Telephone (CANUTEC): (613) 996-6666
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Material Safety Data Sheet
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Document id : 10-2818-2 Issue date : 01/09/2005
Version : 7.00 Supersedes date : 22/08/2005
Copyright, 1997, 3M Canada Company. All rights reserved. Copying
and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information
is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold
or otherwise distributed with the intention of earning a profit
thereon.
Prepared by: Environmental Health and Safety Services Department, 3M
Canada Company
Telephone: (519) 452-2161, Fax: (519) 452-6015, Web Site: www.3M.ca
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1 Product Identification
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Tradename:
3M(TM) TROUBLESHOOTER(TM)
Product ID:
FZ-0100-0465-8 FZ-0100-0466-6 61-5000-0313-4 61-5000-6131-4
96-0000-0066-9 70-0709-9784-9 CN-1006-1045-6 CN-1006-4512-2
XN-1015-5593-8 XN-1015-5594-6 CN-1006-2976-1 70-0709-9783-1
Intended Use of Product:
Cleaner;
Division:
COMMERCIAL CARE DIVISION
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2 Composition/Information on Ingredients
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Ingredient Name CAS Number Percentage
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WATER 7732-18-5 60 - 90
2-BUTOXYETHANOL 111-76-2 10 - 30
ISOBUTANE 75-28-5 5 - 10
ETHANOLAMINE 141-43-5 3 - 7
PROPANE 74-98-6 0.5 - 1.5
NOTE:
Each percentage is expressed as the ratio of the weight of the
ingredient to the weight of the controlled product.
3M(TM) TROUBLESHOOTER(TM) Page 2 of 8
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3 Hazards Identification
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Critical Hazards:
Aerosol container contains flammable gas under pressure.
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Harmful by inhalation.
May be absorbed following inhalation and cause target organ
effects.
See Sections 7 and 11 for further information.
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4 First Aid Measures
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Instructions for Eye Contact:
Flush eyes with large amounts of water. Get medical attention.
Instructions for Skin Contact:
Wash affected area with soap and water. If signs/symptoms develop,
get medical attention.
Instructions for Inhalation:
If signs/symptoms develop, remove person to fresh air. If
signs/symptoms persist, get medical attention.
Instructions for Ingestion:
Do not induce vomiting. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get immediate
medical attention.
Special Instructions:
Exposure may increase myocardial irritability. Do not administer
sympathomimetic drugs unless absolutely necessary.
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5 Fire Fighting Measures
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Flash point: Nil (NON-FLAMMABLE ACCORDING
TO FLAME PROJECTION TEST)
Lower Explosive Limit (%): Not Available
Upper Explosive Limit (%): Not Available
Autoignition temperature: Not Available
Suitable Extinguishing Media:
Use fire extinguishers with class B extinguishing agents (e.g., dry
chemical, carbon dioxide).
Exposure Hazards during Fire:
Closed containers exposed to heat from fire may build pressure and
explode. Vapours may travel long distances along the ground or
floor to an ignition source and flash back.
Combustion Products from Fire:
Carbon monoxide - During Combustion;
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Carbon dioxide - During Combustion;
Irritant Vapours or Gases - During Combustion;
Oxides of Nitrogen - During Combustion;
Fire Fighting Procedures:
Water may not effectively extinguish fire; however, it should be
used to keep fire-exposed containers and surfaces cool and prevent
explosive rupture. Wear full protective equipment (Bunker Gear) and
a self-contained breathing apparatus (SCBA).
NFPA: Health 2
NFPA: Fire 4
NFPA: Reactivity 0
NFPA: Unusual Reaction Hazard none
Special Instructions:
Aerosol container contains flammable material under pressure.
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6 Accidental Release Measures
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Personal Precautions:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation,
and personal protective equipment. Call 3M-HELPS line
(1-800-364-3577) for more information on handling and managing the
spill.
Spill Response:
Ventilate the area with fresh air. Remove all ignition sources such
as flames, smoking materials, and electrical spark sources. Use
only non-sparking tools. For large spill, or spills in confined
spaces, provide mechanical ventilation to disperse or exhaust
vapors, in accordance with good industrial hygiene practice.
Warning! A motor could be an ignition source and could cause
flammable gases or vapors in the spill area to burn or explode.
Contain spill. Cover spill area with a fire-extinguishing foam
designed for use on solvents, such as alcohols and acetone, that
can dissolve in water. An AR - AFFF type foam is recommended.
Dilute in a large excess of water. Carefully, and with stirring,
add appropriate dilute acid such as sulfamic acid or vinegar.
Confirm neutrality. For large spills, if necessary, get assistance
from professional spill clean up team. For small spills, carefully
neutralize spill by adding appropriate dilute acid such as vinegar.
Work slowly to avoid boiling or spattering. Continue to add
neutralizing agent until reaction stops. Let cool before
collecting. Or use a commercially available caustic (alkaline or
basic) spill clean-up kit. Follow kit directions exactly. Remember,
adding an absorbent material does not remove a toxic, corrosivity
or flammability hazard. Collect as much of the spilled material as
possible using non-sparking tools. Clean up residue with detergent
and water. Collect the resulting residue containing solution. Place
in a closed container approved for transportation by appropriate
authorities. Cover, but do not seal for 48 hours. Seal the
3M(TM) TROUBLESHOOTER(TM) Page 4 of 8
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container. Dispose of collected material as soon as possible.
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7 Handling and Storage
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Storage Requirements:
Do not store containers on their sides.
Incompatible Materials:
Store away from heat; Store out of direct sunlight. Sparks and/or
Flames; Store away from acids; Store away from oxidizing agents.
Ventilation:
No data available.
Fire Prevention:
Aerosol container contains flammable gas under pressure. Do not
spray near flames or sources of ignition.
Explosion Prevention:
Keep away from heat, sparks, open flame, pilot lights and other
sources of ignition.
Use Instructions:
Do not pierce or burn container, even after use. Avoid contact with
oxidizing agents.
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8 Exposure Controls/Personal Protection
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Personal Protection
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Eye Protection:
Avoid eye contact with vapours, mists, or spray. The following
should be worn alone or in combination, as appropriate, to prevent
eye contact: Indirect vented goggles;
Hand Protection:
Avoid skin contact.
Skin Protection:
Avoid skin contact.
Respiratory Protection:
Avoid breathing of vapours, mists or spray.
Ingestion (Prevention):
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water. Keep out of the reach of
children.
Recommended Ventilation:
Do not use in a confined area or areas with little or no air
movement. Use general dilution ventilation and/or local exhaust
ventilation to control airborne exposures to below Occupational
Exposure Limits and/or control mist, vapor, or spray. If
ventilation is not adequate, use respiratory protection equipment.
Ingredient Exposure Data
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WATER (7732-18-5)
LD50 (rat, oral) >90 ml/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
2-BUTOXYETHANOL (111-76-2)
LD50 (rat, oral) 470 mg/kg
LD50 (dermal, rabbit) 99 mg/kg
LC50 (rat, inhalation/4 hours) 450 ppm
Exposure Limits
ACGIH: TWA (Table A3) 25 ppm
ISOBUTANE (75-28-5)
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
1000 ppm ACGIH: TWA
ETHANOLAMINE (141-43-5)
LD50 (rat, oral) 1720 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
ACGIH: TWA 3 ppm
ACGIH: TWA 7.5 mg/m3
ACGIH: STEL 6 ppm
ACGIH: STEL 15 mg/m3
PROPANE (74-98-6)
Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
ACGIH: TWA 1000 ppm
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9 Physical and Chemical Properties
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Physical form,Color,Odour: Liquid; Aerosol; off-white;
milky;
Odour Threshold: No data available.
pH: 11 -12
Boiling point/boiling range: Approx100 C
Melting point/melting range: Not applicable
Vapour pressure: Not Available
Water Solubility: Complete
Specific gravity: Approx1 Water=1
Vapour density: Not Available
Volatile organic compounds: 18 -49 % CARB
Evaporation rate: Not Available
Viscosity: Not Available
3M(TM) TROUBLESHOOTER(TM) Page 6 of 8
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Percent Volatile: 78 -100 %
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10 Stability and Reactivity
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Conditions to Avoid:
Store away from heat; Store out of direct sunlight. Sparks and/or
Flames;
Materials to Avoid:
Strong oxidizing agents; Strong acids;
Hazardous Decomposition:
Carbon monoxide - During Combustion;
Carbon dioxide - During Combustion;
Irritant Vapours or Gases - During Combustion;
Oxides of Nitrogen - During Combustion;
Stability and Reactivity:
Stable. Hazardous polymerization will not occur.
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11 Toxicological Information
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Effects from Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Effects from Skin Contact:
Mild Skin Irritation: Signs/symptoms can include localized redness,
swelling, and itching.
Effects from Inhalation:
Harmful by inhalation.
Cardiac Sensitization: Signs/symptoms may include irregular
heartbeat (arrhythmia), faintness, chest pain, and may be fatal.
Single overexposure, above recommended guidelines, may cause: Upper
Respiratory Tract Irritation: Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
May be absorbed following inhalation and cause target organ effects.
Effects from Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal
pain, nausea, diarrhea and vomiting.
Sensitization Information:
No data available.
Carcinogenicity:
No data available.
Mutagenicity:
No data available.
Reproductive Effects:
No data available.
Component Based Information:
No data available.
3M(TM) TROUBLESHOOTER(TM) Page 7 of 8
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Product Based Information:
No data available.
Other Effects & Information:
Single exposure, above recommended guidelines, may cause: Central
Nervous System (CNS) Depression: Signs/symptoms may include
headache, dizziness, drowsiness, incoordination, nausea, slowed
reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure, above recommended guidelines, may
cause: Liver Effects: Signs/symptoms may include loss of appetite,
weight loss, fatigue, weakness, abdominal tenderness and jaundice.
Kidney Effects: Signs/symptoms may include reduced or absent urine
production, increased serum creatinine, lower back pain, increased
protein in urine, and increased blood urea nitrogen (BUN).
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12 Ecological Information
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Environmental Data:
Ecotoxicity Data:
Not determined.
Ecofate Data:
Not determined.
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13 Disposal Considerations
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Product as Sold:
Incinerate in an industrial or commercial facility. As a disposal
alternative, dispose of waste product in a facility permitted to
accept chemical waste. Facility must be capable of handling aerosol
cans. Dispose of empty product containers in a sanitary landfill.
Product Packaging:
No data available.
Special Instructions:
Since regulations vary, consult applicable regulations or
authorities before disposal.
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14 Transportation Information
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Transportation of Dangerous Goods
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TDG Classification: Consumer Commodity
International Dangerous Goods Classification
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15 Regulatory Information
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WHMIS Classification: A, D1A, D2B,
NOTE:
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations (CPR) and the MSDS
contains all the information required by the CPR.
Product Certifications:
The product on this MSDS, or all its components, is included on the
following countries' chemical inventories, as noted:
CICS - Chinese Inventory of Chemical Substances
PICCS - Philippines Inventory of Commercial Chemical Substances
EINECS - European Inventory of Existing Commercial Chemical
Substances
AICS - Australian Inventory of Chemical Substances
TSCA - Toxic Substances Control Act (USA)
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16 Other Information
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Reason for Reissue:
The following Sections and topics have been updated or revised:
WHMIS Classification change
The information in this Material Safety Data Sheet (MSDS) is believed
to be correct as of the date issued. 3M MAKES NO WARRANTIES,
EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT
LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is
fit for a particular purpose and suitable for user's method of use or
application. Given the variety of factors that can affect the use
and application of a 3M product, some of which are uniquely within
the user's knowledge and control, it is essential that the user
evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or
application.
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